Saturday, July 4, 2015

CRYSTALLOGRAPHY PART 2


THE EXTERNAL FEATURES OF A CRYSTAL
The external features of a crystal comprise the following:
Faces, Edges, forms, habits and interfacial angles.
a)    Faces:
Faces are flat and smooth surfaces bounding or enclosing a crystal.  The faces on a crystal are usually well arranged in a regular manner which is related to the internal arrangement of the atoms.  There are two kinds of faces which are like and unlike faces
-         Like faces, are those which have the same size and shape in a regularly developed crystal (that is faces which have the same properties and dimensions).Like faces are common in minerals that crystallize in the cubic system.
-         Unlike facesare those which do not have similar sizes and shapes.  They therefore have different patterns of atoms within them.

b)    Forms:
Form refers to the assemblage of faces within a crystal which together may wholly or partially constitute the exterior of a crystal.  Some crystals can be made up entirely of like faces while other crystals can be made up of like and unlike faces.  The form of a crystal can be described as open or close.
-         Closed form or Simple form: A form is closed if it is made up entirely of like faces (faces which close space by themselves)for example a cubic form has 6 like faces.
-         Open form: A form is said to be open if it has a combination of like and unlike faces for example Beryl has an open form made up of both pyramidal and prismatic faces.

c)     Edges:
An edge of a crystal is a line of intersection of 2 adjacent faces.  The position of an edge depends on the position of the faces that produce the intersection.
d)    Solid angles or Nodes:
A solid angle or node is formed by the intersection of 3 or more faces.
e)     Habit:
This is the characteristic shape of a crystal produced by a variation in the number, size and shape of its faces. For example a cube would assume a cubic habit while octahedrons assume octahedral habits.  The habit of a crystal is influenced by the environment and conditions under which the crystal grew or was formed.  For example Calcite usually has a rhombohedron habit but may assume a scalenohedron.
f)      Interfacial angles

 An interfacial angle is the angle between the normals or perpendiculars of 2 adjacent faces.
 
  

Figure 3: Interfacial Angle



Measuring Interfacial angles
Interfacial angles are measured using an instrument called a Goniometer.  There are two kinds of goniometers which are the Contact and Reflective goniometers.  The contact goniometer (Figure 4) is used for large crystals while the reflective goniometer is used for small crystals with flawless or smooth faces.






 





 
Figure 4: A Contact Goniometer



How the Contact Goniometer is used
The contact goniometer consists of two straight edged arms which are movable on a pivot or screw and connected to a graduated arc similar to that of a protractor.
          The measurements are carried out by bringing the 2 arms firmly and accurately into contact with the adjacent faces of the crystal (Figure 5) and the angle between read off from the graduated arc. 
          The angle that is actually measured is the internal angle (perpendicular to the 2 faces) and must be subtracted from 180o to obtain the interfacial angle.

 

Figure 5: Using the Contact Goniometer



The Law of constancy of Interfacial angles
In 1669, [1]Steno, after studying the interfacial angles on different samples of quartz, put forward the law of constancy of interfacial angles which states that:
For all crystals of a given mineral, the interfacial angles between any two given faces are always constant (the same)”

This law only holds if they are made up of the same chemical composition and measurements are done at the same temperature.

Geologists have been able to predict that crystals are built up by an orderly arrangement of atoms forming rows which correspond to crystal faces.  The faces intersect at the edges which correspond to the intersection of the atomic rows within the crystals.  This means that for all crystals of the same mineral, the faces and edges are always the same (as in the quartz crystal).  Careful studies of crystals have shown that the atomic structure for the crystals of any one mineral is fixed; consequently, the positions of the faces of such crystals are fixed.  Thus based on measurements, the tendency for corresponding interfacial angles to be constant for all the crystals of a given mineral brings about the “Law of constancy of interfacial angles”.

Zonation:
A zone is a set of faces or a collection of faces which are parallel to a given direction.  This direction is termed the zone axis.

A zone axis is a direction in which faces belonging to the same crystal zone are parallel to.



 
Figure 6: Zones and Zone axes


From above, there are three zone axes (X, Y and Z) and therefore the faces can be divided into three zones as follows:
-         Zone 1 consists of faces A, C, A1,C1; the zone axis is X
-         Zone 2 consists of faces A, B, A1, B1; the zone axis is Y
-         Zone 3 consists of faces B, C, B1, C1; the zone axis is Z

Faces in the same zone must not necessarily be adjacent to each other.  However, their edges must be parallel to each other.





[1] Nicholas Steno was a Danish scientist (that is From Denmark)

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